Volatility smirk
Often, the shape of the volatility smile for options on shares or an index is called a "volatility smirk", because of its ascending line.

Chart: Volatility smirk for DJX (expiration in April 2003).
The volatility smirk shows that deep in-the-money calls and deep out-the-money puts cost more than theoretically forecasted by the Black- Sholes formula, while deep out-the-money calls and deep in-the-money puts cost less. This type of shape of the volatility smile reveals that options sellers believe it is much more likely to suffer losses from selling out-the-money puts than out-the money calls.
The shape of a volatility curve also depends on the number of days remaining until expirations. In most cases the smile becomes more clearly defined as expiration approaches. (See volatility charts for OSX for May 2003 and December 2003)

Chart: Volatility curve for OSX (expiration in December 2003).

Chart: Volatility curve for OSX (expiration in May 2003).
Note, the volatility of call can differ from the volatility of put with the same strike and expiration; It indicates the market's bias toward calls or puts. On the site you can see the volatility smile for call and put options displayed separately. If the ratio of Call Volatility to Put Volatility is greater than 100%, it means that Calls are priced higher than Puts. This shows that the market has a positive bias toward the upside. If the ratio of Call Volatility to Put Volatility is less than 100%, then puts are being valued higher. A large difference or spread between call and put volatilities often suggests a strong bias in the market's opinion of the stock.
Volatility time skew
Volatility time skew occurs where options with the same strike but with different number of days remaining until expiration have different volatility.

Chart: Volatility time skew for ATM options on DJX.